New Bibenzyl Cannabinoid from the New Zealand Liverwort Radula marginata.

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  • Toyota Masao
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University
  • Shimamura Takuji
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University
  • Ishii Hikari
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University
  • Renner Matt
    Plant Systematics, School of Biological Sciences, University of Auckland
  • Braggins John
    Plant Systematics, School of Biological Sciences, University of Auckland
  • Asakawa Yoshinori
    Faculty of Pharmaceutical Sciences, Tokushima Bunri University

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Description

The ether extract of the New Zealand liverwort Radula marginata afforded a new cannabinoid type bibenzyl compound named perrottetinenic acid, and two new bibenzyls, together with a known cannabinoid, perrottetinene. Their structures were established by two dimensional (2D) NMR spectral data. The structure of perrottetinenic acid was a similar to that of Δ1-tetrahydrocannabinol, a known hallucinogen. Cannabinoid type bibenzyls have been isolated from liverwort Radula perrottetii, though have not previously been reported from the liverwort R. marginata.

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