ChemInform Abstract: Effects of Magnesium Salts and Amines on the Stereoselectivity in the Imine Aldol Reaction.
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- Hayashi Kazuhiko
- College of Pharmacy, Kinjo Gakuin University
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- Kujime Eiko
- College of Pharmacy, Kinjo Gakuin University
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- Katayama Hajime
- College of Pharmacy, Kinjo Gakuin University
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- Sano Shigeki
- Graduate School of Pharmaceutical Sciences, The University of Tokushima
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- Nagao Yoshimitsu
- Graduate School of Pharmaceutical Sciences, The University of Tokushima
書誌事項
- タイトル別名
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- Effects of Magnesium Salts and Amines on the Stereoselectivity in the Imine Aldol Reaction
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説明
In the imine aldol reactions of 1 with aromatic aldehydes using magnesium salts in the presence of amines, the threo/erythro ratios of products increased in the order Mg(ClO4)2>MgI2>MgBr2>MgCl2>Mg(OTf)2 and N,N,N′,N′-tetramethylethylenediamine (TMEDA)>Et3N. This increase in the threo/erythro ratios of products was estimated to be caused by a retro-imine aldol reaction under thermodynamic control.
収録刊行物
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- ＣＨＥＭＩＣＡＬ ＆ ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ ＢＵＬＬＥＴＩＮ
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ＣＨＥＭＩＣＡＬ ＆ ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ ＢＵＬＬＥＴＩＮ 55 (12), 1773-1775, 2007
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390001204168630016
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- NII論文ID
- 110006532126
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- NII書誌ID
- AA00602100
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- ISSN
- 13475223
- 15222667
- 00092363
- 09317597
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- NDL書誌ID
- 9274205
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- PubMed
- 18057758
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- 本文言語コード
- en
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