Crotalionosides A-C, Three New Megastigmane Glucosides, Two New Pterocarpan Glucosides and a Chalcone C-Glucoside from the Whole Plants of Crotalaria zanzibarica

DOI Web Site Web Site 3 Citations 13 References
  • Shitamoto Junko
    Department of Pharmacognosy, Graduate School of Biomedical Sciences, Hiroshima University
  • Matsunami Katsuyoshi
    Department of Pharmacognosy, Graduate School of Biomedical Sciences, Hiroshima University
  • Otsuka Hideaki
    Department of Pharmacognosy, Graduate School of Biomedical Sciences, Hiroshima University
  • Shinzato Takakazu
    Subtropical Field Science Center, Faculty of Agriculture, University of the Ryukyus
  • Takeda Yoshio
    Faculty of Pharmacy, Yasuda Women's University

Bibliographic Information

Other Title
  • Crotalionosides A–C, three new megastigmane glucosides, two new pterocarpan glucosides amd a chalcone C-glucoside from the whole plants of Crotalaria zanzibarica

Search this article

Abstract

From a 1-BuOH-soluble fraction of the MeOH extract of the leaves of Crotalaria zanzibarica collected in the Okinawa Islands, three new megastigmane glucosides, named crotalionosides A—C, two new pterocarpan glucosides and a chalcone C-glucoside were isolated together with two known flavonoid glycosides and one known megastigmane glucoside. The structures of the new compounds were elucidated by a combination of spectroscopic analyses. The absolute configurations of allenic megastigmane glucosides were determined by application of the modified Mosher's method. Those of the allenic moieties were determined by interpretation of the circular dichroism (CD) spectra of the reduction products derived from citrosides A and B. The aglycones of pterocarpan glucosides were found to be melilotocarpan B and the absolute structure of the chalcone C-glucoside was determined by comparison of the CD spectral behavior with the reported values.

Journal

Citations (3)*help

See more

References(13)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top