An Efficient Catalytic Oxidation of p-Alkoxypenols to p-Quinones Using Tetrabutylammonium Bromide and Oxone

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  • Yakura Takayuki
    Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
  • Ozono Ayaka
    Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
  • Morimoto Kohei
    Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama

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Abstract

A catalytic oxidation of p-alkoxyphenols was developed using tetrabutylammonium bromide (TBAB) and Oxone®. The reaction of p-alkoxyphenol (1) with a catalytic amount of TBAB in the presence of Oxone® as a co-oxidant in acetonitrile–water (2 : 1) gave the corresponding p-quinone (2) in excellent yield without special treatment.

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