Neutron and X-Ray Diffraction Studies of a Valence Fluctuating Compound YbInCu4

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  • Neutron and X-Ray Diffraction Studies of a Valence Fluctuating Compound YbInCu<SUB>4</SUB>
  • Neutron and X Ray Diffraction Studies o

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The crystal structure of YbInCu4 has been refined by the Rietveld analysis of TOF neutron powder diffraction data. This compound has a cubic AuBe5 (C15b, F\bar43m)-type structure with the lattice constant a=7.1575(6) Å, and Yb ions are completely ordered at the 4c site. X-ray powder diffraction data have also been taken as a function of temperature. The lattice constant shows an abrupt change of 0.15% at the temperature of Yb valence phase transition (about 40 K) without any change in the crystal symmetry.

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