First Synthesis of Saponarin, 6-C- and 7-O-Di-β-D-glucosylapigenin
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- Misawa Kazufumi
- Graduate School of Science and Engineering, Yamagata University
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- Takahashi Yasuko
- Graduate School of Science and Engineering, Yamagata University
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- Sato Shingo
- Graduate School of Science and Engineering, Yamagata University
書誌事項
- タイトル別名
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- First Synthesis of Saponarin, 6-<i>C</i>- and 7-<i>O</i>-Di-<i>β</i>-D-glucosylapigenin
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抄録
Saponarin, apigenin 6-C- and 7-O-bis-β-D-glucoside, was synthesized in an overall yield of 37% via 11 steps, which included the C-glycosylation of 2,4-O-dibenzylphloroacetophenone, the introduction of a cinnamoyl residue by aldol condensation, the formation of a flavone by regioselective deprotection, and oxidative ring-closure to the final regioselective deprotection and stereoselective O-glycosylation.
収録刊行物
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- CHEMICAL & PHARMACEUTICAL BULLETIN
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CHEMICAL & PHARMACEUTICAL BULLETIN 61 (7), 776-780, 2013
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390001204177546112
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- NII論文ID
- 130003360803
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- NII書誌ID
- AA00602100
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- COI
- 1:STN:280:DC%2BC3sjmsV2jtA%3D%3D
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- ISSN
- 13475223
- 00092363
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- NDL書誌ID
- 024644945
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- PubMed
- 23812402
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可