Communications to the Editor : A Fluorinated Cobalt(Ⅲ) Porphyrin Complex for Hydroalkoxylation of Alkynes

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  • Ushimaru Richiro
    Department of Chemistry, Graduate School of Science, Nagoya University
  • Nishimura Takuho
    Department of Chemistry, Graduate School of Science, Nagoya University
  • Iwatsuki Toshiki
    Department of Chemistry, Graduate School of Science, Nagoya University
  • Naka Hiroshi
    Department of Chemistry, Graduate School of Science, Nagoya University Research Center for Materials Science, Nagoya University

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  • A Fluorinated Cobalt(III) Porphyrin Complex for Hydroalkoxylation of Alkynes

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<p>A fluorinated cobalt(III) porphyrin complex [Co(TPFPP)NTf2·2C2H5OH, where TPFPP=5,10,15,20-tetrakis(pentafluorophenyl)porphyrin, Tf=CF3SO2] promotes hydroalkoxylation of alkynes to give acetals in good to excellent yields. The acetals can be directly functionalized with nucleophiles in a one-pot procedure.</p>

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