Partial Conductivities of a Molten Salt Based on Langevin Equation.

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  • Koishi Takahiro
    Graduate School of Science and Technology, Niigata University, Niigata 950–2181
  • Tamaki Shigeru
    Department of Physics, Faculty of Science, Niigata University, Niigata 950–2181

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Abstract

Based on the Langevin equations for cations and anions in amolten salt, the ionic partial conductivities are discussed inconnection with their masses. These partial conductivities areshown in terms of current-current correlation functions as anextension of Kubo theory. And these partial conductivities arealso described in terms of conductivity tensors which areintroduced from the macroscopic irreversible thermodynamicviewpoint. These theoretical results are justified by themolecular dynamics simulations carried out for molten NaCl andNaI.

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