Parity-Forbidden Transitions of Deoxyheme

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  • Parity Forbidden Transitions of Deoxyhe

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The parity-forbidden transitions of deoxyheme via the A2u and Eu modes are investigated. The possible transitions are 5B2g5Eg, 5Eg5A1g, 5Eg5B1g, 1A1g1Eg (8062 cm−1) and 1A1g1Eg (20902 cm−1). The variations of the oscillator strengths with respect to temperatures are calculated for these transitions. The theoretically obtained optical spectra are fairly well agree with the experimental ones observed by Kobayashi and Yanagawa.

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