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- Terauchi Hikaru
- Department of Physics, Kwansei Gakuin University
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- Sakai Tooru
- Department of Chemistry, Kobe University
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- Yamada Yasusada
- College of General Education, Osaka University
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説明
The orthorhombic to monoclinic phase transition of aniline-HBr crystal has been investigated with X-ray scattering technique to clarify the mechanism of the phase transition. The temperature dependence of monoclinic angle below the transition indicates the occurrence of ferroelasticity in this substance. The temperature dependence and the q-dependence of the X-ray critical scattering show that a transverse optical mode as well as the uniform transverse acoustic mode becomes unstable at the transition. The phase transition is discussed in terms of the coupling of the three systems: NH3+ ion having an order-disorder freedom of motion, shear strain, and internal displacement of ion described by the TO-mode.
収録刊行物
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 48 (1), 177-184, 1980
一般社団法人 日本物理学会
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詳細情報 詳細情報について
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- CRID
- 1390001204183869440
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- NII論文ID
- 210000088513
- 110001964713
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- NII書誌ID
- AA00704814
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- BIBCODE
- 1980JPSJ...48..177T
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- COI
- 1:CAS:528:DyaL3cXhtlyqsLk%3D
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- ISSN
- 13474073
- 00319015
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- NDL書誌ID
- 2166001
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDLサーチ
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- 使用不可