Incommensurately Modulated Structure of K2SeO4

  • Yamada Noboru
    Department of Applied Physics, Faculty of Engineering, Tohoku University
  • Ikeda Takuro
    Department of Applied Physics, Faculty of Engineering, Tohoku University

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タイトル別名
  • Incommensurately Modulated Structure of K<SUB>2</SUB>SeO<SUB>4</SUB>
  • Incommensurately Modulated Structure of

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The modulated structure in the incommensurate phase of K2SeO4 has been analyzed at 113 K by X-ray diffractometry based on the concept of four-dimensional space. The final R-factor was 0.046 for all 905 reflections and 0.087 for 326 satellite reflections.<BR>The modulation is characterized by the rotation of SeO4 groups around b-direction and the associated translation of K atoms along c-axis. The eigenvector of the modulation mode was determined from the observed atomic displacement pattern and it is compared with that of Σ2 soft mode determined by neutron experiment.

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