Direct Observation of Covalency between O and Disordered Pb in Cubic PbZrO<sub>3</sub>
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- Aoyagi Shinobu
- Department of Physics, Okayama University, Okayama 700-8530
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- Kuroiwa Yoshihiro
- Department of Physics, Okayama University, Okayama 700-8530
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- Sawada Akikatsu
- Department of Physics, Okayama University, Okayama 700-8530
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- Tanaka Hiroshi
- Department of Materials Science, Shimane University, Matsue 690-8504
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- Harada Jimpei
- X-ray Research Laboratory, Rigaku Corporation, Akishima, Tokyo 196-8666
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- Nishibori Eiji
- Department of Applied Physics, Nagoya University, Nagoya 464-8603
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- Takata Masaki
- Department of Applied Physics, Nagoya University, Nagoya 464-8603
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- Sakata Makoto
- Department of Applied Physics, Nagoya University, Nagoya 464-8603
書誌事項
- タイトル別名
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- Direct Observation of Covalency between O and Disordered Pb in Cubic PbZrO3.
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In cubic PbZrO3, which undergoes an antiferroelectric phase transition, the distinct disorder of Pb at twelve sites toward the neighboring O is detected for the first time by analyzing high-energy X-ray powder diffraction data. In the charge density distributions, the covalent nature of the Pb-O bond is also revealed, which proves the existence of electron hybridization between O and disordered Pb in cubic PbZrO3. None of these structural characteristics of PbZrO3 were found in the previously studied cubic PbTiO3 structure [Y. Kuroiwa et al.: Phys. Rev. Lett. 87 (2001) 217601], which undergoes a ferroelectric phase transition. This may be a clue to understanding why PbTiO3 and PbZrO3 respectively show ferroelectric and antiferroelectric phase transitions.
収録刊行物
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 71 (10), 2353-2356, 2002
一般社団法人 日本物理学会
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詳細情報 詳細情報について
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- CRID
- 1390001204185205632
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- NII論文ID
- 210000103884
- 10010898464
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- NII書誌ID
- AA00704814
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- BIBCODE
- 2002JPSJ...71.2353A
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- COI
- 1:CAS:528:DC%2BD38XotFemsLc%3D
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- ISSN
- 13474073
- 00319015
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- NDL書誌ID
- 6332571
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可