An Anomaly in the Magnetic Susceptibility of an Organic Ion-Radical Salt:Triethylammonium-〔TCNQ〕2

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  • An Anomaly in the Magnetic Susceptibility of an Organic Ion-Radical Salt: Triethylammonium-[TCNQ]<SUB>2</SUB>
  • Anomaly in the Magnetic Susceptibili

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Magnetic susceptibility of an organic ion-radical salt, triethylammonium-[TCNQ]2, has precisely been measured in the temperature range between 4.2 and 360 K. It shows a shallow but obvious dip near 215 K. Such anomaly in the susceptibility of the salt has been found for the first time. The anomaly may result from the change of the nature of spin dynamics in the salt. The susceptibility cannot be explained in a wide temperature range including 215 K by a simple spin-pair model.

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