Uniaxial Compression of the Halogen-Bridged Binuclear Metal Complex Pt2(n-butylCS2)4I
-
- Ito Hiroshi
- Department of Applied Physics, Nagoya University
-
- Hasegawa Yasuhisa
- Department of Applied Physics, Nagoya University
-
- Tanaka Hisaaki
- Department of Applied Physics, Nagoya University
-
- Kuroda Shin-ichi
- Department of Applied Physics, Nagoya University
-
- Mitsumi Minoru
- Department of Material Science, Himeji Institute of Technology
-
- Toriumi Koshiro
- Department of Material Science, Himeji Institute of Technology
Bibliographic Information
- Other Title
-
- Uniaxial Compression of the Halogen-Bridged Binuclear Metal Complex Pt<sub>2</sub>(<i>n</i>-butylCS<sub>2</sub>)<sub>4</sub>I
Search this article
Abstract
Resistance measurements under uniaxial compression have been performed on the quasi-one-dimensional iodo-bridged diplatinum complex (MMX-chains) Pt2(n-butylCS2)4I between 100–355 K. The first-order phase transition between the low-temperature alternate-charge-polarization (ACP) state and room-temperature average-valence (AV) state (210 K at ambient pressure) shifted to a higher temperature under compression both parallel and perpendicular to the MMX chains. The stabilization of the ACP state by both compression directions indicates that the ligand molecules play a significant role in making the valence ordering state.
Journal
-
- Journal of the Physical Society of Japan
-
Journal of the Physical Society of Japan 72 (9), 2149-2152, 2003
THE PHYSICAL SOCIETY OF JAPAN
- Tweet
Details 詳細情報について
-
- CRID
- 1390001204187496832
-
- NII Article ID
- 210000104408
- 110001974298
- 130004538496
-
- NII Book ID
- AA00704814
-
- BIBCODE
- 2003JPSJ...72.2149I
-
- ISSN
- 13474073
- 00319015
-
- NDL BIB ID
- 6684829
-
- Text Lang
- en
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed