Stark Effect of the Absorption Line of Methane Observed by the 3.391 μm He–Ne Maser

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  • Stark effect of the absorption line of methane observed by the 3.391 ミュー m He-Ne maser

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Abstract

The Stark effect in CH4 which has no permanent dipole moment in the ground vibrational state is observed on one component line at 2947.802 cm−1 of the P(7) line in the ν3 band by a magnetically tuned infrared maser. The effect is interpreted on the basis of the second-order induced dipole moment in the degenerate vibrational state which has the F2 symmetry. The magnitude of the induced dipole moment of CH4 in the ν3 vibrational mode is evaluated from the observed Stark effect.

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