Phase Transition in Crystals of Semiflexible Long-Chain Molecules. II
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- Ishinabe Takao
- Faculty of Engineering, Yamagata University
書誌事項
- タイトル別名
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- Phase Transition in Crystals of Semiflexible Long-Chain Molecules. I
説明
A theory based on Kirkwood’s mean-field approximation is presented in order to elucidate the nature of a solid-state phase transition associated with rotational fluctuations about chain axes. Simultaneous equations describing states of the system are obtained and are solved for several restricted cases. A first-order phase transition with the latent heat of 19 cal/CH2mol is predicted at 339 K for C22 n-paraffine; it well explains the empirical rotational phase transition, but the latent heat is far less than experimental values.
収録刊行物
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- Ｊｏｕｒｎａｌ ｏｆ ｔｈｅ Ｐｈｙｓｉｃａｌ Ｓｏｃｉｅｔｙ ｏｆ Ｊａｐａｎ
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Ｊｏｕｒｎａｌ ｏｆ ｔｈｅ Ｐｈｙｓｉｃａｌ Ｓｏｃｉｅｔｙ ｏｆ Ｊａｐａｎ 43 (2), 627-633, 1977
一般社団法人 日本物理学会
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詳細情報 詳細情報について
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- CRID
- 1390001204189562752
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- NII論文ID
- 210000086932
- 210000087693
- 130003737511
- 130003737218
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- COI
- 1:CAS:528:DyaE2sXlsVChtrs%3D
- 1:CAS:528:DyaE1cXlslajsLg%3D
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- ISSN
- 13474073
- 00319015
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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- 抄録ライセンスフラグ
- 使用不可
