Drastic Change of Magnetic Phase Diagram in Doped Quantum Antiferromagnet TlCu1-xMgxCl3

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  • Drastic Change of Magnetic Phase Diagram in Doped Quantum Antiferromagnet TlCu1−xMgxCl3
  • Drastic Change of Magnetic Phase Diagram in Doped Quantum Antiferromagnet TlCu<sub>1-<i>x</i></sub>Mg<sub><i>x</i></sub>Cl<sub>3</sub>

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TlCuCl3 is a coupled spin dimer system, which has a singlet ground state with an excitation gap of Δ⁄gμB=5.5 T. TlCu1−xMgxCl3 doped with nonmagnetic Mg2+ ions undergoes impurity-induced magnetic ordering. Because triplet excitation with a finite gap still remains, this doped system can also undergo magnetic-field-induced magnetic ordering. Through specific heat measurements and neutron scattering experiments under a magnetic field, we investigated the phase diagram in TlCu1−xMgxCl3 with x∼0.01, and found that impurity- and field-induced ordered phases are the same. The gapped spin liquid state observed in pure TlCuCl3 is completely wiped out by the small amount of doping.

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