Giant Negative Magnetoresistance Reflecting Molecular Symmetry in Dicyano(phthalocyaninato)iron Compounds

  • Hanasaki N.
    Institute for Solid State Physics, University of Tokyo
  • Matsuda M.
    Institute for Solid State Physics, University of Tokyo
  • Tajima H.
    Institute for Solid State Physics, University of Tokyo
  • Ohmichi E.
    Institute for Solid State Physics, University of Tokyo
  • Osada T.
    Institute for Solid State Physics, University of Tokyo
  • Naito T.
    Division of Chemistry, Hokkaido University
  • Inabe T.
    Division of Chemistry, Hokkaido University

書誌事項

公開日
2006
DOI
  • 10.1143/jpsj.75.033703
公開者
一般社団法人 日本物理学会

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説明

Materials containing Fe(Pc)(CN)2 dicyano(phthalocyaninato)iron molecules show a giant negative magnetoresistance from the interaction between the conduction and the local moment. Under a magnetic field, the resistance becomes two orders of magnitude smaller than the zero-field resistance. The magnetic-field-angle dependence of the magnetoresistance reflects the symmetry of the Fe(Pc)(CN)2 molecule. We discuss, according to the scaling relation, the correlation between the magnetoresistance and the molecular spin fluctuation.

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