N.Q.R.Zeeman spectra of bromine in p-bromophenol and p-bromoaniline

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  • N.Q.R. Zeeman Spectra of Bromine in <I>p</I>-Bromophenol and <I>p</I>-Bromoaniline

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Zeeman effect of Br79 and Br81 nuclear quadrupole resonance had been carried out at room temperature in single crystals of p-bromophenol and p-bromoaniline. Two inequivalent field gradient systems are observed in both the compounds. The asymmetry parameter of the field gradient is determined to be 0.07±0.03 and 0.08±0.03 for p-bromophenol and p-bromoaniline respectively. The minimum number of the molecules in the unit cell, the orientation of the molecular plane and the C–Br bond characters are estimated in both the compounds.

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