Theory of Thermodynamic Properties of Liquid Metals

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Thermodynamic properties of simple liquid metals investigated from the fundamental point of view of the electron theory of metals. Modified from of the pressure equation appropriate to liquid metals is applied to the calculations of the thermal pressure coefficient and the thermal expansion coefficient of simple metals using the pseudopotential formalism for the electron-ion interaction. Comparisons of the predictions and experiments are made and the agreement is found satisfactory for the simpler metals.

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