Synthesis of ordered mesoporous carbons by a soft-templating method
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- Nishiyama Norikazu
- Graduate School of Engineering Science, Osaka University
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- Tanaka Shunsuke
- Department of Chemical, Energy and Environmental Engineering, Faculty of Environmental and Urban Engineering, Kansai University
Bibliographic Information
- Other Title
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- ソフトテンプレート法による規則性メソポーラスカーボンの合成
- ソフト テンプレートホウ ニ ヨル キソクセイ メソポーラスカーボン ノ ゴウセイ
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Abstract
Ordered mesoporous carbons were synthesized by using an organic-organic self-assembly (soft-templating) method using resorcinol (R) / formaldehyde (F) and triblock copolymer Pluronic F127. A hexagonal mesostructure with channel like pores (COU-1) with a pore size of 4.7–5.8 nm and a 3D wormhole-like mesopore structure (COU-2) with a pore size of 4.8 nm were synthesized using precursor solutions with different mass ratios of F127/RF resin. The mesoporous carbons were activated by using KOH to improve their porosity. The KOH-activated COU-2 carbon showed superior capacitance compared to the COU-2 carbon and a commercial microporous carbon. Ultrathin carbon films with a monolayer of uniform mesopores were also synthesized on a silicon substrate by contacting a triblock copolymer film with a benzyl alcohol vapor followed by carbonization.
Journal
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- TANSO
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TANSO 2011 (247), 70-74, 2011
THE CARBON SOCIETY OF JAPAN
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Details 詳細情報について
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- CRID
- 1390001204226166784
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- NII Article ID
- 10028178247
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- NII Book ID
- AN00140335
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- ISSN
- 18845495
- 03715345
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- HANDLE
- 10112/5670
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- NDL BIB ID
- 11076544
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- Data Source
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- JaLC
- IRDB
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed