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- 松尾 吉晃
- 兵庫県立大学大学院工学研究科物質系工学専攻
書誌事項
- タイトル別名
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- Preparation and applications of new intercalation compounds of graphite oxide
- サンカ コクエン オ ホスト ト スル シンキソウ カン カゴウブツ ノ ゴウセイ ト オウヨウ
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The preparation and application of new intercalation compounds of graphite oxide are reviewed. Graphite oxide was silylated with different silylating reagents such as alkyltrichlorosilane and 3-aminopropylethoxysilanes. After they were bidentately or monodentately attached to layers of graphite oxide, Si-OH groups which are available for further functionalization were introduced. When highly silylated graphite oxide was heated under vacuum, microporous or mesoporous pillared carbons in which adjacent carbon layers are connected with siloxane or silsesquioxane pillars were obtained. Organic molecules were size-selectively intercalated into the pillared carbon obtained from graphite oxide silyated 3 times with methyltrichlorosilane. The excess hydrogen adsorption of pillared carbons at ambient temperature reached 0.6 wt% at 20 MPa. Pillared carbon thin films were prepared and they showed a selective electrical resistance change response to electron donating and smaller organic molecules.
収録刊行物
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- 炭素
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炭素 2014 (263), 109-113, 2014
炭素材料学会
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詳細情報 詳細情報について
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- CRID
- 1390001204229718016
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- NII論文ID
- 130004812827
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- NII書誌ID
- AN00140335
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- ISSN
- 18845495
- 03715345
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- NDL書誌ID
- 025606020
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可