Investigation of the sp³ structure of carbon fibres using UV-Raman spectroscopy
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- Tanaka Fumihiko
- Composite Materials Research Laboratories, TORAY Industries, Inc.
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- Wolverson Daniel
- Department of Physics, University of Bath
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- Okabe Tomonaga
- Department of Aerospace Engineering, Tohoku University
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- Kinloch Ian A.
- School of Materials, University of Manchester
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- Young Robert J.
- School of Materials, University of Manchester
書誌事項
- タイトル別名
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- Investigation of the <i>sp</i><sup>3</sup> structure of carbon fibres using UV-Raman spectroscopy
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We have used UV-Raman spectroscopy to study the sp3 structure in polyacrylonitrile- and pitch-based carbon fibres with Young's modulus values in the range of 90-830 GPa. The composite microstructure of these carbon fibres comprises an amorphous carbon phase that transfers the load to a reinforcing graphite crystalline phase. The intensity ratio of the T, D and G Raman bands showed that the low modulus polyacrylonitrile-based carbon fibres (Young's modulus=200-300 GPa) contained 10-25% sp3 carbon, whereas the stiffer polyacrylonitrile-based carbon fibres (Young's modulus >350 GPa) contained ∼5% sp3 material. This result suggests that the proportion of sp3 carbon decreases as the amorphous structure is converted into a crystalline structure during the carbonization treatment, leading to the high performance fibres. This observation is consistent with our current understanding of the relationship between structure and mechanical properties in carbon fibres.
収録刊行物
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- 炭素
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炭素 2013 (259), 243-247, 2013
炭素材料学会
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詳細情報 詳細情報について
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- CRID
- 1390001204229754112
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- NII論文ID
- 10031194847
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- NII書誌ID
- AN00140335
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- ISSN
- 18845495
- 03715345
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- NDL書誌ID
- 024868673
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可