Annealing-induced devitrification behavior of a Ti47.4Zr5.3Ni5.3Cu42.0 glassy alloy
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- Seki Ichiro
- Institute for Materials Research, Tohoku University
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- Fukuhara Mikio
- Institute for Materials Research, Tohoku University
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- Kawashima Asahi
- Institute for Materials Research, Tohoku University
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- Kimura Hisamichi
- Institute for Materials Research, Tohoku University
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- Inoue Akihisa
- Institute for Materials Research, Tohoku University
書誌事項
- タイトル別名
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- Annealing-Induced Devitrification Behavior of a Ti<SUB>47.4</SUB>Zr<SUB>5.3</SUB>Ni<SUB>5.3</SUB>Cu<SUB>42.0</SUB> Glassy Alloy
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抄録
We have investigated devitrification behavior, accompanied by glass transition and precipitation of crystallites, as a function of annealing temperature and time for a Ti47.4Zr5.3Ni5.3Cu42.0 glassy alloy sheet, together with embrittlement behavior using bending fracture strain test. From kinetic analysis in one DSC profile under a constant heating rate, we can easily estimate the devitrification with temperature and time upon annealing. The glassy alloy became brittle during progressive devitrification in accordance with kinetic estimation. In sharp contrast with a Zr55Al10Ni5Cu30 glassy alloy, all the precipitations of crystallites (Cu4Ti3, Ti and CuTi) occur above glass transition temperature (Tg). We found that the Ti-based glassy alloy has large structurally and thermally stable area, which does not brittle up to 1.10×104 s at 650 K and 1.29×1010 s at 600 K, by experiment and kinetic estimation, respectively.
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 48 (9), 2459-2463, 2007
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390001204249576064
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- NII論文ID
- 10019853858
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- NII書誌ID
- AA1151294X
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 8885379
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可