Synthesis and hydrogen storage behaviour of pure Mg2FeH6 at nanoscale
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- Zhang Xuanzhou
- Department of Materials Physics and Chemistry, University of Science and Technology Beijing Beijing National Laboratory for Molecular Sciences (BNLMS), (The State Key Laboratory of Rare Earth Materials Chemistry and Applications), College of Chemistry and Molecular Engineering, Peking University
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- Tian Wenhuai
- Department of Materials Physics and Chemistry, University of Science and Technology Beijing
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- Yang Junzhi
- Beijing National Laboratory for Molecular Sciences (BNLMS), (The State Key Laboratory of Rare Earth Materials Chemistry and Applications), College of Chemistry and Molecular Engineering, Peking University
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- Yang Rong
- Beijing National Laboratory for Molecular Sciences (BNLMS), (The State Key Laboratory of Rare Earth Materials Chemistry and Applications), College of Chemistry and Molecular Engineering, Peking University
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- Zheng Jie
- Beijing National Laboratory for Molecular Sciences (BNLMS), (The State Key Laboratory of Rare Earth Materials Chemistry and Applications), College of Chemistry and Molecular Engineering, Peking University
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- Li Xingguo
- Beijing National Laboratory for Molecular Sciences (BNLMS), (The State Key Laboratory of Rare Earth Materials Chemistry and Applications), College of Chemistry and Molecular Engineering, Peking University
書誌事項
- タイトル別名
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- Synthesis and Hydrogen Storage Behaviour of Pure Mg<SUB>2</SUB>FeH<SUB>6</SUB> at Nanoscale
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抄録
Pure Mg2FeH6 compounds with two different morphologies have been successfully synthesized directly by mechanical milling (MM) and sintering of a mixture of 2Mg+Fe nanoparticles under an H2 atmosphere, respectively. The successful preparation of pure Mg2FeH6 can be attributed to the small particle sizes of Mg and Fe nanoparticles prepared by hydrogen plasma-metal reaction (HPMR), which provides shorter diffusion distance for hydrogen and the metals. The X-ray diffraction (XRD) and scanning electron microscopy (SEM) results show that the Mg2FeH6 synthesized by mechanical milling has larger particle size but smaller crystallite size compared with the Mg2FeH6 synthesized by sintering. The Mg2FeH6 synthesized by mechanical milling can desorb more than 4.5 mass% hydrogen in 10 min under an initial hydrogen pressure of 0.001 bar at 573 K. Compared with the Mg2FeH6 synthesized by sintering under the same conditions as the Mg2FeH6 synthesized by mechanical milling, it is suggested that decrease of crystallite size is beneficial for enhancing desorption property of Mg2FeH6.
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 52 (4), 618-622, 2011
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390001204251450880
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- NII論文ID
- 10028174929
- 130004454667
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- NII書誌ID
- AA1151294X
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 11058197
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
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- 使用不可