The structure of an Al-Ni-Ru monoclinic phase Al13(Ru,Ni)4

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  • Murao Reiko
    Institute for Materials Research, Tohoku University
  • Genba Michiyo
    Department of Earth and Planetary Science, Graduate School of Science, The University of Tokyo
  • Sugiyama Kazumasa
    Institute for Materials Research, Tohoku University
  • Sun Wei
    Institute of Microstructure and Property of Advanced Materials, Beijing University of Technology

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  • The Structure of an Al-Ni-Ru Monoclinic Phase Al<SUB>13</SUB>(Ru,Ni)<SUB>4</SUB>

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The structure of a Ni-substituted Al13(Ru,Ni)4 phase was analyzed by single crystal X-ray diffraction. The present analysis revealed the distribution of Ni at five heavy metal sites of Ru/Ni(1), Ru/Ni(2), Ru/Ni(3), Ru/Ni(4) and Ru/Ni(5). The anisotropic contraction of the corresponding coordination polyhedra around heavy metal sites was also suggested together with a variation of lattice constants as a function of Ni content.

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