Raman and Infrared Spectroscopic Studies on Li₄RuH₆ Combined with First-Principles Calculations
-
- Sato Toyoto
- Institute for Materials Research, Tohoku University
-
- Takagi Shigeyuki
- Institute for Materials Research, Tohoku University
-
- Matsuo Motoaki
- Institute for Materials Research, Tohoku University
-
- Aoki Katsutoshi
- Institute for Materials Research, Tohoku University
-
- Deledda Stefano
- Physics Department, Institute for Energy Technology
-
- Hauback Bjørn C.
- Physics Department, Institute for Energy Technology
-
- Orimo Shin-ichi
- WPI-Advanced Institute for Materials Research, Tohoku University
書誌事項
- タイトル別名
-
- Raman and Infrared Spectroscopic Studies on Li<sub>4</sub>RuH<sub>6</sub> Combined with First-Principles Calculations
この論文をさがす
抄録
We have studied the vibrational properties of Li4RuH6, consisting of the lightest Li+ metal cation, and the octahedral [RuH6]4− complex anion by Raman and Fourier Transform Infrared (FTIR) spectroscopies and first-principles calculations. The Li+ forms a cubic framework with the [RuH6]4− inside as the local atomic arrangement of Li4RuH6, which is similar to that of a related M′2RuH6 with a divalent metal cation M′ (M′ = Mg, Ca, Sr, Ba, and Yb). Comparing the vibrational studies on Li4RuH6 with M′2RuH6, the peak frequencies for the antisymmetric Ru–H stretching mode (νanti-str) showed a reasonable relationship with the Ru–H bond distances (dRu–H) in [RuH6]4−, with higher peak frequencies for shorter bond distances according to the linear relation νanti-str = 10052 − 4990 × (dRu–H).
収録刊行物
-
- MATERIALS TRANSACTIONS
-
MATERIALS TRANSACTIONS 55 (8), 1117-1121, 2014
公益社団法人 日本金属学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390001204253707520
-
- NII論文ID
- 130004455350
-
- NII書誌ID
- AA1151294X
-
- ISSN
- 13475320
- 13459678
-
- NDL書誌ID
- 025616832
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
-
- 抄録ライセンスフラグ
- 使用不可