Silver-selective Sensor Using an Electrode-separated Piezoelectric Quartz Crystal Modified with a Chitosan Derivative.

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  • BAO Shanhu
    Department of Chemistry, Faculty of Science, Shinshu University
  • NOMURA Toshiaki
    Department of Chemistry, Faculty of Science, Shinshu University

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Silver(I) adsorbed selectively onto a quartz plate modified with N-(2-pyridylmethyl)chitosan in an ammonium chloride buffer solution containing EDTA, and the frequency of the quartz plate increased. It was supposed that the increasing frequency was caused by the desorption of adsorbed water on the chitosan derivative, which was induced from the reaction of silver(I) with the chitosan derivative. The concentration of the buffer, pH, temperature, conductivity and eluent affected the frequency shift resulting from the adsorption of silver(I). The frequency decreased at a conductivity lower than 2.2 mS/cm, and increased with increasing conductivity above this value. The frequency shifts caused by the adsorption of silver(I) were proportional to the concentration over the range 10 - 80 nM of silver(I), and the correlation coefficient was 0.9969. The detection limit and the relative standard deviation at 50 nM for five times were 6 nM and 3.4%, respectively. The proposed method was simple while showing higher sensitivity and selectivity.

収録刊行物

  • Analytical Sciences

    Analytical Sciences 18 (8), 881-885, 2002

    社団法人 日本分析化学会

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