Perfluorocarbon-based Liquid-Liquid Extraction for Separation of Transition Metal Ions

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  • MARUYAMA Tatsuo
    Department of Applied Chemistry, Graduate School of Engineering and Center for Future Chemistry, Kyushu University
  • NAKASHIMA Kazunori
    Department of Applied Chemistry, Graduate School of Engineering and Center for Future Chemistry, Kyushu University
  • KUBOTA Fukiko
    Department of Applied Chemistry, Graduate School of Engineering and Center for Future Chemistry, Kyushu University
  • GOTO Masahiro
    Department of Applied Chemistry, Graduate School of Engineering and Center for Future Chemistry, Kyushu University

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抄録

We report a liquid-liquid extraction system based on perfluorocarbon (fluorous-solvent extraction) that allows selective extraction of metal ions from aqueous and organic phases to a perfluorocarbon phase (FC-72) with perfluorinated β-diketone (1,1,1,5,5,6,6,6-octafluoro-2,4-hexanedione), which can be followed by backward extraction using 1 M nitric acid.

収録刊行物

  • Analytical Sciences

    Analytical Sciences 23 (7), 763-765, 2007

    社団法人 日本分析化学会

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