Tunable Selectivity of Lanthanide Ion Exchange within a Coordination Polymer

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  • TASAKI-HANDA Yuiko
    Research Institute for Environmental Management Technology, National Institute of Advanced Industrial Science and Technology (AIST)
  • OOI Kenta
    Research Institute for Environmental Management Technology, National Institute of Advanced Industrial Science and Technology (AIST)
  • TANAKA Mikiya
    Research Institute for Environmental Management Technology, National Institute of Advanced Industrial Science and Technology (AIST)
  • WAKISAKA Akihiro
    Research Institute for Environmental Management Technology, National Institute of Advanced Industrial Science and Technology (AIST)

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The exchange of lanthanide(III) ions (Ln3+) between a solution and a coordination polymer (CP) formed by cerium(III) or samarium(III) ion and an organophosphorous ligand has been studied. The CPs exhibit distinctive Ln3+ affinity that varies with a small change in its framework, depending on the central Ln3+.

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  • Analytical Sciences

    Analytical Sciences 29 (7), 685-687, 2013

    社団法人 日本分析化学会

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