Chemiluminescence Detection of Glucose Using Ce(IV) Oxidation in a Batch System
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- NAGAI Megumi
- Separation Science Division, Faculty of Science, Okayama University of Science
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- MIYAHARA Wakayo
- Separation Science Division, Faculty of Science, Okayama University of Science
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- SAGAWA Honami
- Separation Science Division, Faculty of Science, Okayama University of Science
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- YAMAZAKI Shigeo
- Separation Science Division, Faculty of Science, Okayama University of Science
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- SAITO Keiitsu
- Division of Natural Environment and Chemistry, Faculty of Human Development, Kobe University
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説明
A chemiluminescence method for the determination of glucose (GC) using a batch system made in our laboratory is proposed. The method is based on measures of the chemiluminesence intensity from a batch of sample GC solutions following the injection of an (NH4)2[Ce(NO3)6]–[Ru(bpy)3]Cl2 solution. The effect of the Ru complex concentration on chemiluminescence was studied. The detection limit was 0.5 × 10−8 M, and the linear calibration curve reached 10−7 M. The Ru complex was selected on the basis of its desirable performance compared to those of other photosensitizers. However, flow-injection analysis (FIA) using the Ce-Ru complex reagent was not applicable for the detection of GC.
収録刊行物
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- Analytical Sciences
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Analytical Sciences 29 (1), 21-24, 2013
社団法人 日本分析化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204259255296
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- NII論文ID
- 10031147320
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- NII書誌ID
- AA10500785
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- COI
- 1:STN:280:DC%2BC3s3otFKntw%3D%3D
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- ISSN
- 13482246
- 09106340
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- NDL書誌ID
- 024212022
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- PubMed
- 23303079
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可