Analysis of Distribution and Intraparticle Diffusion of a Fluorescent Dye in Mesoporous Silica Gel by Confocal Fluorescence Microspectroscopy
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- SATO Tatsumi
- Division of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba
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- NAKATANI Kiyoharu
- Division of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba
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抄録
A micrometer-sized spherical silica gel microparticle (pore diameter, ∼7 nm) was injected into an aqueous rhodamine 6G solution using microcapillary manipulation-injection technique, and the dye distribution in the single microparticle was measured as the fluorescence depth profile by confocal fluorescence microspectroscopy. The fluorescence depth profile was simulated by the convolution and deconvolution methods to correct the contribution of the spatial resolution of the experimental system. The dye homogeneously or heterogeneously distributed in the microparticle at the adsorption equilibrium, dependent on the type of silica gel. The intraparticle diffusion coefficient of the dye distributed homogeneously in the silica gel was analyzed by the simulations of the time dependence of the fluorescence depth profile based on the external and intraparticle diffusion model. The results indicated that the intraparticle diffusion of the dye in the silica gel is governed by the pore diffusion.
収録刊行物
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- Analytical Sciences
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Analytical Sciences 33 (2), 179-183, 2017
社団法人 日本分析化学会
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詳細情報
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- CRID
- 1390001204260743552
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- NII論文ID
- 130005316201
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- NII書誌ID
- AA10500785
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- ISSN
- 13482246
- 09106340
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- NDL書誌ID
- 027968903
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- PubMed
- 28190837
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可