New Determination Methods of Halides and Cyanide Ions by Electrospray Ionization Mass Spectrometry Based on Ternary Complex Formation
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- HOTTA Hiroki
- Department of Chemistry, Nara University of Education
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- KURIHARA Shota
- Department of Chemistry and Chemical Biology, Gunma University
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- JOHNO Keita
- Department of Chemistry and Chemical Biology, Gunma University
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- KITAZUME Masaomi
- Department of Chemistry and Chemical Biology, Gunma University
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- SATO Kiichi
- Department of Chemistry and Chemical Biology, Gunma University
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- TSUNODA Kin-Ichi
- Department of Chemistry and Chemical Biology, Gunma University
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Abstract
Determination methods of halide ions (X− = F−, Cl−, Br− and I−) by electrospray ionization mass spectrometry (ESIMS) were developed, where negative ions of the ternary complexes of group-13 elements, nitrilotriacetic acid (NTA), and halides were measured. In particular, these halides were simultaneously determined by measuring [InX(nta)]−, and the limits of detection (LODs) were 1.1 μmol dm−3 for F−, 0.32 μmol dm−3 for Cl−, 3.8 nmol dm−3 for Br−, and 1.6 nmol dm−3 for I−, respectively. This approach was extended to the determination of CN−, where the ternary complex of CuII, CN− and 4-(2-pyridylazo)resorcinol (PAR), i.e., [63CuII(CN)(par)]− (m/z 302) was measured. The LOD for CN− was 20 nmol dm−3.
Journal
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- Analytical Sciences
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Analytical Sciences 27 (9), 953-, 2011
The Japan Society for Analytical Chemistry
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Details 詳細情報について
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- CRID
- 1390001204261159808
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- NII Article ID
- 10029761255
- 130004442064
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- NII Book ID
- AA10500785
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- ISSN
- 13482246
- 09106340
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- HANDLE
- 20.500.14094/90004308
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- NDL BIB ID
- 11235332
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- PubMed
- 21908926
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- Text Lang
- en
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- Data Source
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- JaLC
- IRDB
- NDL
- Crossref
- PubMed
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed