ダイオキシン類の生成・分解挙動に対するS02添加効果の熱力学的解釈
書誌事項
- タイトル別名
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- The Effect of Sulfur Dioxide Addition on Dioxins Generation and Decomposition Behaviors from Thermodynamics View.
説明
The influence of sulfur dioxide addition on dioxins generation and decomposition behaviors has been evaluated by thermodynamic equilibrium calculations. The calculation conditions in this work were as follows: (1) the C-H-O-Cl quaternary system has the ratio of [C : H : O : Cl]=9 : 6 : 4 : 1, i.e. this system corresponds to the most typical generation region of dioxins, (2) total amount of respective elements (NC+NH+NO+NCl) is 1 mol, (3) sulfur dioxide is then added to this C-H-O-Cl quaternary system and (4) total pressure and temperature range were 1 atm and from 773 to 1773 K. The influence of sulfur dioxide addition is shown to change the oxygen potential, on which the dioxins generation and decomposition is independent, i.e. higher temperature and higher oxygen potential lead to dioxins decomposition. The essential effect of sulfur element is shown to reduce hydrogen chloride potential, leading less dioxins chlorination reaction.
収録刊行物
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- 資源処理技術
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資源処理技術 49 (1), 16-22, 2002
一般社団法人 環境資源工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204267501056
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- NII論文ID
- 130003440719
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- ISSN
- 18839150
- 09124764
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可