Non-ionic Photoacid Generators Sensitive to 365nm Light-Synthesis and Applications to Photocrosslinking Systems-
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- Shirai Masamitsu
- Department of Applied Chemistry, Osaka Prefecture University
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Abstract
Non-ionic photoacid generators (PAG) based on imino sulfonates and N-hydroxyimide sulfonates were designed and synthesized. To obtain the PAGs sensitive to 365 nm light, fluorenone oxime, thioxanthone oxime and N-hydroxyimide derivatives of thioxanthone were used as a chromophore. The PAGs obtained were thermally stable and highly photosensitive. A mechanism for the photolysis of the PGAs was discussed. Some of the thioxanthone-based PAGs were sensitive to 436 nm light. Photocrosslinking of poly(glycidyl methacrylate) using the PAG was also studied.
Journal
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 20 (5), 615-620, 2007
The Society of Photopolymer Science and Technology(SPST)
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Details 詳細情報について
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- CRID
- 1390001204323827456
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- NII Article ID
- 130004464594
- 40015602538
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- NII Book ID
- AA11576862
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- COI
- 1:CAS:528:DC%2BD2sXot1Wmsbk%3D
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- ISSN
- 13496336
- 09149244
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- NDL BIB ID
- 8918794
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed