Self-Consistent Field Theory of Directed Self-Assembly on CH Pitch Division

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We have done SCFT simulations to investigate the directed self-assembly on CH pitch division. The structural change by the thickness Lz of oval prepattern reveals that perpendicular cylinders are favored when Lz is not commensurate with the distance between cylinders L0. In this case linear rows of cylinders are along major radius for narrow ovals, and wider ovals tend to pack additional rows of cylinders in a staggered hexagonal arrangement. Sweeping from neutral to PMMA attractive substrates causes a transition from cylinders that penetrate completely through the film, to cylinders that terminate in nearly spherical caps. Thus a neutral substrate would be favorable in order to get cylinders that penetrate completely through the film.

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