Development of a Novel Preparation Method for Highly Porous Heat-Resistant Rigid Polymer Network Films and Evaluation of their Properties
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- Uchida Tetsuya
- Graduate School of Natural Science and Technology, Okayama University
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- Ikeda Ryo
- Graduate School of Natural Science and Technology, Okayama University
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- Suzuki Tomoaki
- Graduate School of Natural Science and Technology, Okayama University
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- Nakayama Ryotaro
- Graduate School of Natural Science and Technology, Okayama University
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抄録
A rigid polymer network of poly(p-phenylene benzobisoxazole) (PBO) has excellent mechanical properties and thermal stability. Many nano voids exist within the network. However, a PBO network cannot be formed into films or fibers. Generally, PBO networks are prepared by one-step polycondensation in polyphosphoric acid. In this study, we have prepared a PBO network by a two-step method involving polymerization of a PBO network precursor (pre-PBO network) in N-methyl-2-pyrrolidone followed by thermal cyclization. Heat-resistant porous PBO network films have been successfully obtained by this two-step method. The properties of the PBO network films have been evaluated.
収録刊行物
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 28 (2), 163-167, 2015
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詳細情報 詳細情報について
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- CRID
- 1390001204324965376
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- NII論文ID
- 130005093840
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- NII書誌ID
- AA11576862
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- ISSN
- 13496336
- 09149244
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- NDL書誌ID
- 026578519
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可