Synthesis and Mechanofluorochromism of 4-[Bis(4-methylphenyl)amino]acetophenone
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- Okoshi Kenji
- Department of Applied Chemistry, Muroran Institute of Technology
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- Nakano Hideyuki
- Department of Applied Chemistry, Muroran Institute of Technology
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In order to create a new mechanofluorochromic material, title compound (BMAAP) was designed and synthesized. BMAAP was found to readily form an amorphous glass with a glass transition temperature of 9 °C and exhibit solvatofluorochromism in solution. BMAAP was also found to exhibit fluorescence both in crystalline state and in amorphous one and the fluorescence color in amorphous state was different from that in crystalline state. Finally, we have found that BMAAP exhibited mechanofluorochromism and the phenomenon was suggested to be caused by morphological change from crystalline state to amorphous one by mechanical grinding.
収録刊行物
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 27 (4), 535-538, 2014
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詳細情報 詳細情報について
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- CRID
- 1390001204325023872
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- NII論文ID
- 130004687624
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- NII書誌ID
- AA11576862
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- ISSN
- 13496336
- 09149244
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- NDL書誌ID
- 025604551
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可