Two-step Radical Grafting onto Polypropylene Fiber Initiated by Active Species Prepared through the Irradiation of Electron Beam
-
- Hisada Kenji
- Graduate School of Engineering, University of Fukui
-
- Matsuoka Misaki
- Graduate School of Engineering, University of Fukui
-
- Tabata Isao
- Faculty of Engineering, University of Fukui
-
- Hirogaki Kazumasa
- Graduate School of Engineering, University of Fukui
-
- Hori Teruo
- Headquarters for Innovative Society-Academia Cooperation, University of Fukui
この論文をさがす
抄録
Graft polymerization is one of the surface modification methods for organic solid. When organic solids are irradiated by electron beam (EB), activation sites can be generated in the polypropylene and monomer reacts at the active site to grafted chains. First-step polymerization proceeded during EB irradiation. And then, the fiber was heated at high pressure to promote second step grafting with high propagation rate. The generated chains have bimodal distribution in molecular weight and high molecular weight component gradually increased with polymerization pressure for second grafting. The molecular weight of grafted chains and their distribution are evaluated from those for the extracted solution polymers. Temperature dependence of grafting efficiency gave us thermodynamic parameters for the grafting polymerization.
収録刊行物
-
- Journal of Photopolymer Science and Technology
-
Journal of Photopolymer Science and Technology 26 (2), 277-282, 2013
フォトポリマー学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390001204325516800
-
- NII論文ID
- 130004465034
- 40019685656
-
- NII書誌ID
- AA11576862
-
- COI
- 1:CAS:528:DC%2BC3sXhtFalu7fJ
-
- ISSN
- 13496336
- 09149244
-
- NDL書誌ID
- 024660461
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
-
- 抄録ライセンスフラグ
- 使用不可