Ambipolar Low-bandgap Copolymers Consisting of Dithienoketopyrrole for All-Polymer Solar Cells
-
- Ide Marina
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University
-
- Koizumi Yoshihiko
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University
-
- Saeki Akinori
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University PRESTO-JST
-
- Seki Shu
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University
この論文をさがす
抄録
The new low-band gap copolymers containing electron-accepting thienoisoindigo (TIDG) exhibit the low-lying lowest unoccupied molecular orbital (LUMO) at -3.8 eV. This envisions their use as n-type polymer in combination with typical p-type regioregular poly(3-hexylthiophene) (P3HT) towards all-polymer organic photovoltaics (OPV). The alternating fluorene and TIDG copolymer, PFTIDG, shows the electronic absorption maximum at 744 nm in the film states, of which spectrum is complementary to that of P3HT and thus advantageous for covering the wide solar spectrum. The laser and Xe-flash time-resolved microwave conductivity (TRMC) evaluations were performed for screening the effects of p/n blend ratio and thermal annealing in bulk heterojunction framework. The power conversion efficiency of 0.06% was obtained for pre-annealed P3HT:PFTIDG = 1:1 together with a high open circuit voltage of 0.92 V, which is suggestive of ambipolar characteristics of PFTIDG.
収録刊行物
-
- Journal of Photopolymer Science and Technology
-
Journal of Photopolymer Science and Technology 26 (2), 217-221, 2013
フォトポリマー学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390001204325543552
-
- NII論文ID
- 130004465023
- 40019685585
-
- NII書誌ID
- AA11576862
-
- COI
- 1:CAS:528:DC%2BC3sXhtFalu7jI
-
- ISSN
- 13496336
- 09149244
-
- NDL書誌ID
- 024660375
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可