Development of Self-Assembling Alternating Amphiphilic Compounds

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  • Muraoka Takahiro
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University,
  • Sadhukhan Nabanita
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University,
  • Li Rui
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University,
  • Kinbara Kazushi
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University,

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Synthesis and self-assembling properties of alternating amphiphilic compounds 1 and 2 were reported. 1 and 2 are consisting of a hydrophilic hexaol core, a tripentaerythritol unit, bearing two hydrophobic aromatic groups at the both ends. DLS measurements displayed that the amphiphiles form micrometer- to submicrometer-scale aggregates in MeOH, where the aromatic and/or hydrophobic interactions likely plays important roles in the self-assembly. This study demonstrated a utility of the tripentaerythritol unit to develop amphiphilic molecules with self-assembling functions.

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