Sensitization of Thianthrenium Salt for Cationic Polymerization of Epoxides

DOI Web Site Web Site 15 References
  • Sakho M.
    Department of Photochemistry, CNRS, University of Haute Alsace
  • Allonas X.
    Department of Photochemistry, CNRS, University of Haute Alsace
  • Ley C.
    Department of Photochemistry, CNRS, University of Haute Alsace

Search this article

Abstract

We evaluated the influence of sensitizers on the reactivity of a thianthrenium salt. Calculating the difference in free energy shows that the decomposition of the salt occurs through electron transfer mechanism. Photopolymerization efficiency was evaluated using real-time RTIR, showing that the sensitization process is effective and that its efficiency is governed by the photoinduced electron transfer reaction.

Journal

References(15)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top