ク形波ポーラログラフ法による銑鉄,鋳鉄中の微量ビスマス定量方法

DOI Web Site Web Site

書誌事項

タイトル別名
  • Determination of a trace of bismuth in cast iron and pig iron
  • クケイハ ポーラログラフホウ ニ ヨル センテツ , チュウテツ チュウ ノ ビリョウ ビスマス テイリョウ ホウホウ
  • Studies on the technoanalytical method by means of S. W. polarograph. IV
  • ク形波ポーラログラフによる分析方法の研究(第4報)

この論文をさがす

抄録

Recent investigation has revealed that a trace of bismuth has an important effect on the nodulizing of graphite in the manufacturing of nodular graphite cast iron, and this makes it necessary to determine an extremely small amount of bismuth in pig iron and cast iron overlooked heretofore.<BR>One g. sample is dissolved in perchloric acidnitric acid mixture and heated to white fuming. The residue is taken up in hydrochloric acid to 68N HCl and the majority of iron is removed by MIBK extraction. After the insoluble material including silica is separated by filtration, the residual iron is extracted with MIBK. The HCl layer is evaporated to dryness and the residue is dissolved in 30ml 0.3N HCl. The solution is transferred into a separatory funnel and the bismuth is adsorbed on 20ml of xylene solution of 10% Amberlite LA-1. The bismuth is liberated with 3N HNO3, concentrated to 1ml and heated with 1ml perchloric acid<BR>The perchloric acid is driven off, 5ml of a supporting reagent (1N HCl+N/500 HCl) is added, and the polarogram on 00.25V (vs. Hg pool) is taken. Bismuth is determined by the aid of a calibration curve preliminarily prepared. 0.0020.0025% bismuth was estimated by the proposed. method.

収録刊行物

  • 分析化学

    分析化学 12 (1), 4-8, 1963

    公益社団法人 日本分析化学会

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ