Monitoring and Characterization of Pyrolysis Gas from Various Polymers Using Skimmer Interface-Connected [TG/DTA]/[Ion Attachment Ionization-TOFMS]
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- MISHIMA Yuji
- Tsurui Chemical Co., Ltd.
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- YOSHIDA Hiromi
- Tsurui Chemical Co., Ltd.
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- HINO Kenji
- Canon ANELVA Co.
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- ONUKI Satomi
- Department of Chemistry, Faculty of Science, Kanagawa University
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- TSUGOSHI Takahisa
- National Institute of Advanced Industrial Science and Technology
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- SAITO Naoaki
- National Institute of Advanced Industrial Science and Technology
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- NISHIMOTO Yuko
- Department of Chemistry, Faculty of Science, Kanagawa University
Bibliographic Information
- Other Title
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- スキマーインターフェースで接続した[TG/DTA]/[イオン付着イオン化-TOFMS]による高分子材料からの熱分解発生ガスのモニタリングと特性評価
- スキマー インターフェース デ セツゾク シタ TG DTA イオン フチャク イオンカ TOFMS ニ ヨル コウブンシ ザイリョウ カラ ノ ネツ ブンカイ ハッセイ ガス ノ モニタリング ト トクセイ ヒョウカ
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Description
Evolved gas analyses by pyrolysis were carried out for 10 kinds of polymers using a newly developed prototype of Skimmer interface-connected [TG/DTA]/[Ion Attachment Ionization-TOFMS]. This prototype has an advantage of the real-time monitoring of pyrolyzed species because of no transformation of the evolved species with the skimmer interface and no fragmentation during ionization by the Ion Attachment Ionization technique. On the other hand, the combination of TG/DTA results and mass spectra offers the discrimination of polymers with the same chemical structure and different thermal properties. Examples were presented in this study.
Journal
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- BUNSEKI KAGAKU
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BUNSEKI KAGAKU 60 (3), 261-267, 2011
The Japan Society for Analytical Chemistry
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Details 詳細情報について
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- CRID
- 1390001204356486528
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- NII Article ID
- 10028106835
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- NII Book ID
- AN00222633
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- COI
- 1:CAS:528:DC%2BC3MXjsV2ltro%3D
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- NDL BIB ID
- 11037511
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- ISSN
- 05251931
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed