Characterization of Silver o-Ethylphosphonate for Oxidizing Reagent and Application to Oxidative Removal of Benzaldehyde in Aromatic Compound

DOI NDL Digital Collections Web Site Web Site 8 References
  • MIYAUCHI Toshiyuki
    Department of Applied Chemistry, College of Engineering, Chubu University
  • KUROKI Kazushi
    Department of Applied Chemistry, College of Engineering, Chubu University
  • ISHIKAWA Norihisa
    Department of Applied Chemistry, College of Engineering, Chubu University
  • TAKAHASHI Makoto
    Department of Applied Chemistry, College of Engineering, Chubu University
  • MORI Hidehiko
    Department of Applied Chemistry, College of Engineering, Chubu University

Bibliographic Information

Other Title
  • ｏ‐エチルホスホン酸銀の酸化能の評価と芳香族化合物中のベンズアルデヒドの酸化除去への応用
  • o-エチルホスホン酸銀の酸化能の評価と芳香族化合物中のベンズアルデヒドの酸化除去への応用
  • o エチルホスホンサンギン ノ サンカノウ ノ ヒョウカ ト ホウコウゾク カゴウブツ チュウ ノ ベンズアルデヒド ノ サンカ ジョキョ エ ノ オウヨウ

Search this article

Description

Silver o-ethylphosphonate was prepared by the reaction of diethylphosphonate with silver nitrate for 8 h in acetonitrile below 10°C. This compound decomposed in alcoholic potassium hydroxide to form silver(II) oxide and ethylphosphonate in the intermediate. When no reducing reagent existed, silver(II) oxide was reduced by ethylphosphonate to deposite silver, which formed a silver film on the glass base. When a reducing reagent existed, it was oxidized by silver(II) oxide. Benzaldehyde and its derivatives with an electron-withdrawing substituent were oxidized to convert corresponding carboxylic acid in a yield of over 90%. This oxidoreduction occurred at room temperature, and finished within 10 minutes. The oxidation reaction of benzaldehyde by silver o-ethylphosphonate could be utilized for the removal of benzaldehyde contained in a liquid aromatic compound. Benzaldehyde <2 v/v% contained in toluene could be removed in a single oxidation reaction, and of 20 v/v% in the operation performed four times.<br>

Journal

  • BUNSEKI KAGAKU

    BUNSEKI KAGAKU 56 (1), 37-41, 2007

    The Japan Society for Analytical Chemistry

References(8)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top