書誌事項
- タイトル別名
-
- Determination of molybdenum using ESR method
- デンシ スピン キョウメイホウ オ モチイタ モリブデン ノ テイリョウホウ
この論文をさがす
抄録
A molybdenum (Mo) thiocyanate complex, Mo(SCN)5 had been used previously for the determination of Mo in seawater using electron spin resonance (ESR) method. In the present ESR study, a reduced Mo complex with diethyldithiocarbamate (DDC), Mo-DDC, was extracted with cycohexanol and used for the determination of Mo. Mo-DDC shows a peak at g = 1.980 with peak-to-peak width of 0.3 mT, whereas Mo(SCN)5 shows a peak at g = 1.940 with peak-to-peak width of 1.2 mT. DDC reacts with Mo more specifically than SCN-: The peak height of Mo-DDC is nearly 30 times that of Mo(SCN)5 produced from the solution containing both DDC and SCN- with the molar ratio of DDC: SCN- = 1 : 30. The limit of detection and the time required for measurement are 0.1 ng and 5 min, respectively in the present method, whereas those are 5 ng and 60 min, respectively in the previous SCN method.
収録刊行物
-
- Biomedical Research on Trace Elements
-
Biomedical Research on Trace Elements 15 (1), 82-84, 2004
日本微量元素学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390001204366344576
-
- NII論文ID
- 130004456748
- 10028287162
-
- NII書誌ID
- AN10423256
-
- ISSN
- 18801404
- 0916717X
-
- NDL書誌ID
- 6914104
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- NDL
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可