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- Bulgarevich Dmitry S.
- Department of Chemical Systems, National Institute of Materials and Chemical Research
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- Sako Takeshi
- Department of Chemical Systems, National Institute of Materials and Chemical Research
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- Sugeta Tsutomu
- Department of Chemical Systems, National Institute of Materials and Chemical Research
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- Otake Katsuto
- Department of Chemical Systems, National Institute of Materials and Chemical Research
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- Sato Masahito
- Department of Chemical Systems, National Institute of Materials and Chemical Research
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- Uesugi Masayuki
- Department of Industrial Chemistry , Faculty of Engineering, Nihon University
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- Kato Masahiro
- Department of Industrial Chemistry , Faculty of Engineering, Nihon University
書誌事項
- タイトル別名
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- Solvent Polarities of Supercritical CO2
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抄録
UV/VIS absorption spectroscopy was used to estimate the microscopic solvent polarities of supercritical carbon dioxide alone and its mixtures with methanol. It was found that the local composition of methanol in the cybotactic region of 4-nitroanisole was larger than the corresponding bulk concentration. With increasing pressure the methanol molecules were pressed out of the solvation shell of probe molecule by the carbon dioxide molecules. From the solubility measurements the solvation numbers of the carbon dioxide molecules around 4-nitroanisole were calculated as a function of fluid density.
収録刊行物
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- 高圧力の科学と技術
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高圧力の科学と技術 7 1423-1425, 1998
日本高圧力学会
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詳細情報 詳細情報について
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- CRID
- 1390001204382140032
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- NII論文ID
- 10002694285
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- NII書誌ID
- AN10452913
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- ISSN
- 13481940
- 0917639X
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- NDL書誌ID
- 4494256
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可