Synthesis of Azetidines from Imines with 2,3-Dihydrofuran under High Pressure.

DOI Web Site 参考文献3件
  • Oishi A.
    National institute of Materials and chemical research
  • Taguchi Y.
    National institute of Materials and chemical research
  • Tsuchiya T.
    National institute of Materials and chemical research
  • Shibuya I.
    National institute of Materials and chemical research

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タイトル別名
  • Synthesis of Azetidines from Imines wit

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6, 7-Aryl-2-oxa-7-azabicyclo[3. 2. 0]heptane compounds were obtained from arylimines with 2, 3-dihydrofuran under high pressure. When benzylidene aniline used as imine, 6, 7-diphenyl-2-oxa-7-azabicyclo[3. 2. 0]heptane was obtained 66% yield with 87% selectivity. This reaction was promoted by pressure and the yield and the selectivity of the reaction were increased by temperature. The mechanism of the reaction was considered zwittenonic route was favored.

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