書誌事項
- タイトル別名
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- Radical-initiated homo- and copolymerization of 2-fluoroacrylonitrile.
- 2 フルオロアクリロニトリル ノ ラジカル ジュウゴウ
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抄録
2-Fluoroacrylonitrile (α-FAN) has been synthesized and homopolymerized by bulk and solution methods. The poly(α-FAN) is a white solid and soluble in various aprotic polar solvents, tetrahydrofuran, and acetone at room temperature. Dehydrofluorination and intramolecular cyclization occurred when poly(α-FAN) was heated to 250∼300°C. The glass transition temperature (Tg) of poly(α-FAN) was observed to be 101°C by thermomechanical analysis (TMA). The relative reactivity ratios in a-FAN (M2) copolymerization with styrene (St) (r1=0.44, r2=0.03) were obtained. Application of Q-e scheme led to Q=0.43 and e=1.28 for α-FAN.
収録刊行物
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- 日本化学会誌（化学と工業化学）
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日本化学会誌（化学と工業化学） 1985 (10), 1862-1868, 1985
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204389195648
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- NII論文ID
- 130004157950
- 40002844209
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- NII書誌ID
- AN00186595
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- ISSN
- 21850925
- 03694577
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- NDL書誌ID
- 3056750
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可