塩化鉄(III)を用いたベンゼンのジフェニルメタノール類によるFriede1-Craftsジフェニルメチル化

書誌事項

タイトル別名
  • Friedel-Crafts' Diphenylmethylation of Benzene with Diphenylmethanols using Iron(III) Chloridet
  • Friedel-Crafts' Diphenylmethylation of Benzene with Diphenylmethanols using Iron(III) Chloride.

説明

When a mixture of diphenylmethamols and iron(III) chloride (FeC13) was heated in benzene, Friedel-Crafts' diphenylmethylation took place to yield triphenylmethanes with the corresponding benzophenones as by-products. The yield of triphenylmethanes could be eleva ted without a formation of benzophenones by adding a small amount of tribenzylamine to the benzene solution of diphenylmethanols and FeC18. Pentylamine and hydroquinone could be used to get more yield of triphenylmethane in the reaction of benzene with diphenylmethanol. t Synthetic Reaction Using Iron(la) Chloride. V.

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